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By Sonia Fernandez - UC Santa Barbara

A new method could get graphene a step closer to replacing less-effective copper interconnects in the world’s computer devices.

Ever since scientists discovered graphene, the flexible, two-dimensional form of graphite (think a 1-atom-thick sheet of pencil lead), in 2004, researchers around the world have been working to develop commercially scalable applications for this high-performance material.

Graphene is 100 to 300 times stronger than steel and has a maximum electrical current density orders of magnitude greater than that of copper, making it the strongest, thinnest and, by far, the most reliable electrically conductive material on the planet. It is, therefore, an extremely promising material for interconnects, the fundamental components that connect billions of transistors on microchips in computers and other electronic devices in the modern world.

The problem with copper

For over two decades, interconnects have been made of copper, but that metal encounters fundamental physical limitations as electrical components that incorporate it shrink to the nanoscale.

“As you reduce the dimensions of copper wires, their resistivity shoots up,” says Kaustav Banerjee, a professor in the electrical and computer engineering department at the University of California, Santa Barbara. “Resistivity is a material property that is not supposed to change, but at the nanoscale, all properties change.”

As the resistivity increases, copper wires generate more heat, reducing their current-carrying capacity. It’s a problem that poses a fundamental threat to the $500 billion semiconductor industry. Graphene has the potential to solve that and other issues. One major obstacle, though, is designing graphene microcomponents that can be manufactured on-chip, on a large scale, in a commercial foundry.

“Whatever the component, be it inductors, interconnects, antennas, or anything else you want to do with graphene, industry will move forward with it only if you find a way to synthesize graphene directly onto silicon wafers,” Banerjee says. He explains that all manufacturing processes related to the transistors, which are made first, are referred to as the ‘front end.’ To synthesize something at the back-end—that is, after the transistors are fabricated—you face a tight thermal budget that cannot exceed a temperature of about 500 degrees Celsius.

If the silicon wafer gets too hot during the back-end processes employed to fabricate the interconnects, other elements that are already on the chip may get damaged, or some impurities may start diffusing, changing the characteristics of the transistors.

Now, after a decade-long quest to achieve graphene interconnects, Banerjee’s lab has developed a method to implement high-conductivity, nanometer-scale doped multilayer graphene (DMG) interconnects that are compatible with high-volume manufacturing of integrated circuits.

Image Credit: Adi Goldstein via Unsplash

Overcoming graphene bottlenecks

Banerjee first proposed the idea of using doped multi-layer graphene in 2008 and has been working on it ever since. In February 2017, he led the experimental realization of the idea by Chemical Vapor Deposition (CVD) of multilayer graphene at a high temperature, subsequently transferring it to a silicon chip, then patterning the multilayer graphene, followed by doping.

Electrical characterization of the conductivity of DMG interconnects down to a width of 20 nanometers established the efficacy of the idea that Banerjee proposed in 2008. However, the process was not “CMOS-compatible” (the standard industrial-scale process for making integrated circuits), since the temperature of CVD processes far exceed the thermal budget of back-end processes.

To overcome this bottleneck, Banerjee’s team developed a unique pressure-assisted solid-phase diffusion method for directly synthesizing a large area of high-quality multilayer graphene on a typical dielectric substrate used in the back-end CMOS process. Solid-phase diffusion, well known in the field of metallurgy and often used to form alloys, involves applying pressure and temperature to two different materials that are in close contact so that they diffuse into each other.

Banerjee’s group employed the technique in a novel way. They began by depositing solid-phase carbon in the form of graphite powder onto a deposited layer of nickel metal of optimized thickness. Then they applied heat (300 degrees Celsius) and nominal pressure to the graphite powder to help break down the graphite. The high diffusivity of carbon in nickel allows it to pass rapidly through the metal film.

How much carbon flows through the nickel depends on its thickness and the number of grains it holds. “Grains” refer to the fact that deposited nickel is not a single-crystal metal, but rather a polycrystalline metal, meaning it has areas where two single-crystalline regions meet each other without being perfectly aligned. These areas are called grain boundaries, and external particles—in this case, the carbon atoms—easily diffuse through them. The carbon atoms then recombine on the other surface of the nickel closer to the dielectric substrate, forming multiple graphene layers.

Banerjee’s group is able to control the process conditions to produce graphene of optimal thickness.

“For interconnect applications, we know how many layers of graphene are needed,” says Junkai Jiang, a PhD candidate in Banerjee’s lab and lead author of the paper. “So we optimized the nickel thickness and other process parameters to obtain precisely the number of graphene layers we want at the dielectric surface.

“Subsequently, we simply remove the nickel by etching so that what’s left is only very high-quality graphene—virtually the same quality as graphene grown by CVD at very high temperatures,” he says. “Because our process involves relatively low temperatures that pose no threat to the other fabricated elements on the chip, including the transistors, we can make the interconnects right on top of them.”

Bottom line: graphene interconnects help to create faster, smaller, lighter, more flexible, more reliable, and more cost-effective integrated circuits.

The researchers presented a paper at the 2018 IEEE International Electron Devices Meeting. A round-up of the paper also appears in Nature Electronics.

Banerjee is currently in talks with industry partners interested in potentially licensing this CMOS-compatible graphene synthesis technology, which could pave the way for what would be the first 2D material to enter the mainstream semiconductor industry. UC Santa Barbara has filed a provisional patent on the process.

Support for the research came from the National Science Foundation, the National Institute of Standards and Technology, Semiconductor Research Corporation, the US Army Research Office, and the University of California Research Initiatives.

Source: UC Santa Barbara via Futurity

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